2014

Reductive Cross-Coupling of 3-Bromo-2,1-borazaronaphthalenes with Alkyl Iodides

Molander, G. A.; Wisniewski, S. R.; Traister, K. M. Org. Lett., 2014, 16, 3692

Accessing 2-(Hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes: Palladium-Catalyzed Cross-Couplings of 2-(Chloromethyl)-2,1-borazaronaphthalenes

Molander, G. A.; Amani, J.; Wisniewski, S. R. Org. Lett., 2014, 16, 6024

Suzuki–Miyaura Cross-Coupling of Brominated 2,1-Borazaronaphthalenes with Potassium Alkenyltrifluoroborates

Molander, G. A.; Wisniewski, S. R.; Etemadi-Davan, E. J. Org. Chem., 2014, 79, 11199

Diastereoselective Synthesis of Vicinally Di-trifluoromethylated Alkylboron Compounds via Successive Insertions of 2,2,2-Trifluorodiazoethane

Molander, G. A.; Ryu, D. Angew. Chem. Int. Ed., 2014, 53, 14181

Accessing an Azaborine Building Block: Synthesis and Substitution Reactions of 2-Chloromethyl-2,1-borazaronaphthalene

Molander, G. A.; Wisniewski, S. R.; Amani, J. Org. Lett., 2014, 16, 5636

Copper(II)-Mediated O-Arylation of Protected Serines and Threonines

El Khatib, M.; Molander, G. A. Org. Lett., 2014, 16, 4944

Accessing 2,1-Borazaronaphthols: Self-Arylation of 1-Alkyl-2-aryl-3-bromo-2,1-borazaronaphthalenes

Molander, G. A.; Wisniewski, S. R. J. Org. Chem., 2014, 79, 8339

Arylation and Heteroarylation of Thienylsulfonamides with Organotrifluoroborates

Noreen, M.; Rasool, N.; El Khatib, M.; Molander, G. A. J. Org. Chem., 2014, 79, 8339

Accessing Molecularly Complex Azaborines: Palladium-Catalyzed Suzuki–Miyaura Cross-Couplings of Brominated 2,1-Borazaronaphthalenes and Potassium Organotrifluoroborates

Molander, G. A.; Wisniewski, S. R. J. Org. Chem., 2014, 79, 6663

Accessing Molecularly Complex Azaborines: Palladium-Catalyzed Suzuki–Miyaura Cross-Couplings of Brominated 2,1-Borazaronaphthalenes and Potassium Organotrifluoroborates

Molander, G. A.; Traister, K. M.; O’Neill, B. T. J. Org. Chem., 2014, 79, 5771

Single-electron Transmetalation in Organoboron Cross-coupling by Photoredox/Nickel Dual Catalysis

Tellis, J. C.; Primer, D. N.; Molander, G. A. Science, 2014, 345, 433

Stereospecific Ni-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with Alkyl Halides

Molander, G. A.; Argintaru, O. A. Org. Lett., 2014, 16, 1904

Carbonylative Suzuki Couplings of Aryl Bromides with Boronic Acid Derivatives under Base-Free Conditions

Bjerglund, K. M.; Skrydstrup, T.; Molander, G. A. Org. Lett., 2014, 16, 1888

A Convergent, Modular Approach to Functionalized 2,1-Borazaronaphthalenes from 2-Aminostyrenes and Potassium Organotrifluoroborates

Wisniewski, S. R.; Guenther, C. L.; Argintaru, O. A.; Molander, G. A. J. Org. Chem., 2014, 79, 365

Copper-Mediated Radical Trifluoromethylation of Unsaturated Potassium Organotrifluoroborates

Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A. J. Org. Chem., 2013, 78, 12837

Synthesis and Applications of α-Trifluoromethylated Alkylboron Compounds

Argintaru, O. A.; Ryu, D.; Aron, I.; Molander, G. A.Angew. Chem. Int. Ed., 2013, 52, 13656

Synthesis and Suzuki–Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl Compounds

Molander, G. A.; Wisniewski, S. R.; Hosseini-Sarvari, M. Adv. Synth. Catal., 2013, 355, 3037

Pd-Catalyzed Alkynylation of 2-Chloroacetates and 2-Chloroacetamides with Potassium Alkynyltrifluoroborates

Molander, G. A.; Traister, K. M. Org. Lett., 2013, 15, 5052

Suzuki–Miyaura Cross-Coupling of Potassium Trifluoro(N-Methylheteroaryl)borates with Aryl and Heteroaryl Halides

Molander, G. A.; Ryu, D.; Hosseini-Sarvari, M.; Devulapally, R.; Seapy, D. G.J. Org. Chem., 2013, 78, 6648

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

Molander, G. A.; Cavalcanti, L. N.; García-García, C.J. Org. Chem., 2013, 78, 6427

Pd-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with 2-Chloroacetates and 2-Chloroacetamides

Molander, G. A.;Barcellos, T.; Traister, K. M.Org. Lett., 2013, 15, 3342

Synthesis of Trifluoromethylated Isoxazolidines: 1,3-Dipolar Cycloaddition of Nitrosoarenes, (Trifluoromethyl)diazomethane, and Alkenes

Molander, G. A.; Cavalcanti, L. N.Org. Lett., 2013, 15, 3166

Pd-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions between Sulfamates and Potassium Boc-Protected Aminomethyltrifluoroborates

Molander, G. A.; Shin, I.Org. Lett., 2013, 15, 2534

Synthesis and Minisci Reactions of Organotrifluoroborato Building Blocks

Presset, M.;Fleury-Brégeot, N.;Oehlrich, D.;Rombouts, F.; Molander, G. A.J. Org. Chem., 2013, 78, 4615

Palladium-Catalyzed α-Arylation of 2-Chloroacetates and 2-Chloroacetamides

Molander, G. A.; Traister, K. M.; Barcellos, T. J. Org. Chem., 2013, 78, 4123

Complementary Regioselectivity in Rh(III)-Catalyzed Insertions of Potassium Vinyltrifluoroborate via C–H Activation: Preparation and Use of 4-Trifluoroboratotetrahydroisoquinolones

Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A.Org. Lett., 2013, 15, 1528

Suzuki–Miyaura Cross-Coupling of Potassium Dioxolanylethyltrifluoroborate and Aryl/Heteroaryl Chlorides

Fleury-Brégeot, N.; Oehlrich, D.; Rombouts, F.; Molander, G. A.Org. Lett., 2013, 15, 1536

Pd-Catalyzed Aldehyde to Ester Conversion: A Hydrogen Transfer Approach

Tschaen, B.; Schmink, J.; Molander, G. A.Org. Lett., 2013, 15, 500

Synthesis of 1-Naphthol via Oxidation of Potassium 1-Naphthyltrifluoroborate

Molander, G. A.; Siddiqui, S. Z.; Fleury-Brégeot, N. Org. Synth., 2013, 90, 153

2012

Suzuki–Miyaura Cross-Coupling of Potassium Alkoxyethyltrifluoroborates: Access to Aryl/Heteroarylethyloxy Motifs

Fleury-Brégeot, N; Presset, M.; Beaumard, F.; Colombel, V.; Oehlrich, D.; Rombouts, F.; Molander G. A.J. Org. Chem., 2012, 77, 10399

Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates

Molander, G. A.; Wisniewski, S. R.J. Am. Chem. Soc., 2012, 134, 16856

Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates

Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.J. Org. Chem., 2012, 77, 8678

Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener

Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.Org. Lett., 2012, 14, 4814

Potassium Boc-Protected Secondary Aminomethyltrifluoroborates: Synthesis and Suzuki–Miyaura Cross-Coupling Reactions

Molander, G. A.; Shin, I. Org. Lett., 2012, 14, 4458

Oxidative Condensations To Form Benzimidazole-Substituted Potassium Organotrifluoroborates

Molander, G. A.; Ajayi, K..Org. Lett., 2012, 14, 4242

Activation of Si–Si Bonds for Copper(I)-Catalyzed Conjugate Silylation

Iannazzo, L.;Molander, G. A. Eur. J. Org. Chem., 2012, 4923

Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid

Molander, G. A.; Trice, S. L. J.; Kennedy, S. M.; Dreher, S. D.; Tudge, M. T. J. Am. Chem. Soc., 2012, 134, 11667

Rapid and Efficient Access to Secondary Arylmethylamines

Fleury-Brégeot, N.; Raushel, J.; Sandrock, D. L.; Dreher, S. D.; Molander, G. A. Chem. Eur. J., 2012, 18, 9564

Suzuki–Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Mesylates

Molander, G. A.; Shin, I. Org. Lett., 2012, 14, 3138

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Dumas1, A. M.; Molander, G. M.; Bode, J. W. Angew. Chem. Int. Ed., 2012, 51, 5683

Nitrosation of Aryl and Heteroaryltrifluoroborates with Nitrosonium Tetrafluoroborate

Molander, G. A.; Cavalcanti, L. N. J. Org. Chem., 2012, 77, 4402

Suzuki Coupling of Potassium Cyclopropyl- and Alkoxymethyltrifluoroborates with Benzyl Chlorides

Colombel, V.; Rombouts, F.; Oehlrich, D.; Molander, G. A. J. Org. Chem., 2012, 77, 2966

Suzuki Coupling of Potassium Cyclopropyl- and Alkoxymethyltrifluoroborates with Benzyl Chlorides

Colombel, V.; Presset, M.; Oehlrich, D.; Rombouts, F.; Molander, G. A. Org. Lett., 2012, 14, 1680

Synthesis and cross-coupling reactions of imidomethyltrifluoroborates with aryl chlorides

Devulapally, R.; Fleury-Brégeot, N.; Molander, G. A.; Seapy, D. G. Tetrahedron Lett., 2012, 53, 1051

2011

Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides

Molander, G. A.; Iannazzo, L. J. Org. Chem., 2011, 76, 9182

Copper-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds with Tetrahydroxydiborane

Molander, G. A.; McKee, S. A. Org. Lett., 2011, 13, 4684

Cross-Coupling of Mesylated Phenol Derivatives with Potassium Cyclopropyltrifluoroborate

Molander, G. A.; Beaumard, F.; Niethamer, T. K. J. Org. Chem., 2011, 76, 8126

Metal-Free Chlorodeboronation of Organotrifluoroborates

Molander, G. A.; Cavalcanti, L. J. Org. Chem., 2011, 76, 7195

Iridium-Catalyzed Allylic Amination Route to α-Aminoboronates: Illustration of the Decisive Role of Boron Substituents

Touchet, S.; Carreaux, F.; Molander, G. A.; Carboni, B.; Bouillon, A. Adv. Synth. Catal., 2011, 353, 3391

Synthesis and Suzuki–Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Halides

Molander, G. A.; Shin, I. Org. Lett., 2011, 13, 3956

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

Molander, G. A.; Colombel, V.; Braz, V. A. Org. Lett., 2011, 13, 1852

Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates

Molander, G. A.; Fleury-Brégeot, N.; Hiebel, M.-A. Org. Lett., 2011, 13, 1694

Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions

Raushel, J.; Sandrock, D. L.; Josyula, K. V.; Pakyz, D.; Molander, G. A. J. Org. Chem., 2011, 76, 2762

Cross-Coupling of Mesylated Phenol Derivatives with Potassium Ammonio- and Amidomethyltrifluoroborates

Molander, G. A.; Beaumard, F. Org. Lett., 2011, 13, 1242

Oxidation of Organotrifluoroborates via Oxone

Molander, G. A.; Cavalcanti, L. N. J. Org. Chem., 2011, 76, 623

Synthesis of the stereogenic triad of the halicyclamine A core

Molander, G. A.; Cadoret, F. Tetrahedron Lett., 2011, 52, 2199

2010

Nickel-Catalyzed Cross-Coupling of Potassium Aryl- and Heteroaryltrifluoroborates with Unactivated Alkyl Halides

Molander, G. A.; Argintaru, O. A.; Aron , I.; Dreher, S. D. Org. Lett., 2010, 12, 5783

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

Molander, G. A.; Trice, S. L. J.; Dreher, S. D. J. Am. Chem. Soc., 2010, 132, 17701

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides

Sandrock, D. L.; Jean-Gérard, L.; Chen, C.-y., Dreher, S. D.; Molander, G. A. J. Am. Chem. Soc., 2010, 132, 17108

Synthesis of Amidomethyltrifluoroborates and Their Use in Cross-Coupling Reactions

Molander, G. A.; Hiebel, M.-A. Org. Lett., 2010, 12, 4876

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Enantiomerically Enriched Potassium β-Trifluoroboratoamides with Various Aryl- and Hetaryl Chlorides

Molander, G. A.; Shin, I.; Jean-Gérard, L. Org. Lett., 2010, 12, 4384

Nickel-Catalyzed C−O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates

Molander, G. A.; Beaumard, F. Org. Lett., 2010, 12, 4022

Synthesis of an Acyltrifluoroborate and Its Fusion with Azides To Form Amides

Molander, G. A.; Raushel, J.; Ellis, N. M. J. Org. Chem., 2010, 75, 4304