List of Publications 2009-2000 Sorted by Year



Y. A. Cho, D.-S. Kim, H. R. Ahn, B. Canturk, G. A. Molander, J. Ham, "Preparation of Potassium Azidoaryltrifluoroborates and Their Cross-Coupling with Aryl Halides," Org. Lett., 11, 4330–4333 (2009).
G. A. Molander, B. Canturk, "Monoligated Palladium Complex Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling," Angew. Chem., Int. Ed., 48, 9240–9261 (2009).
G. A. Molander, L. N. Cavalcanti, B. Canturk, P.-S. Pan, L. E. Kennedy, "Efficient Hydrolysis of Organotrifluoroborates via Silica Gel and Water," J. Org. Chem., 74, 7364–7369 (2009).
G. A. Molander, W. Febo-Ayala, L. Jean-Gérard, "Condensation Reactions to Form Oxazoline-Substituted Potassium Organotrifluoroborates," Org. Lett., 11, 3830–3833 (2009).
G. A. Molander, L. Jean-Gérard, "Use of Potassium β-Trifluoroborato Amides in Suzuki–Miyaura Cross-Coupling Reactions," J. Org. Chem., 74, 5446–5450 (2009).
G. A. Molander, D. L. Sandrock, "Utilization of Potassium Vinyltrifluoroborate in the Development of a 1,2-Dianion Equivalent," Org. Lett., 11, 2369–2372 (2009).
R. A. Olivera. L. Savegnago, C. R. Jesse, P. H. Menezes, G. A. Molander, C. W. Nogueira, "Toxicological Investigation and Antinociceptive Property of Potassium Thiophene-3-Trifluoroborate," Basic Clin. Pharm. Tox., 104, 448–454 (2009).
S. D. Dreher, S.-E. Lim, D. L. Sandrock, G. A. Molander, "Suzuki–Miyaura Cross-Coupling Reactions of Primary Alkyltrifluoroborates with Aryl Chlorides," J. Org. Chem., 74, 3626–3631 (2009).
R. Oliveira, R. Silva, G. Molander, P. Menezes, "1H, 13C, 19F, and 11B NMR Spectral Reference Data of Some Potassium Organotrifluoroborates," Magn. Reson. Chem., 47, 873–878 (2009).
G. A. Molander, B. Canturk, L. Kennedy, "Scope of the Suzuki Miyaura Cross-Coupling Reactions of Potassium Heteroaryltrifluoroborates," J. Org. Chem., 74, 973–980 (2009).
G. A. Molander, L. Jean-Gérard, "Scope of the Suzuki Miyaura Cross-Coupling Reaction of Potassium Organotrifluoroboratoketohomoenolates," J. Org. Chem., 74, 1297–1303 (2009).
G. A. Molander, L. Jean-Gérard, "Scope of the Suzuki Miyaura Cross-Coupling Reaction of Potassium Organotrifluoroboratoketohomoenolates," J. Org. Chem., 74, 1297–1303 (2009).


G. A. Molander, D. L. Sandrock, "Orthogonal Reactivity in Boryl-Substituted Organotrifluoroborates," J. Am. Chem. Soc., 130, 15792–15793 (2008).
G. A. Molander, P. E. Gormisky, "Cross-Coupling of Cyclopropyl- and Cyclobutyltrifluoroborate with Aryl- and Heteroaryl Chlorides," J. Org. Chem., 73, 7481–7485 (2008).
G. A. Molander, N. M. Ellis, "Highly Selective Synthesis of cis-Alkenyl Pinacolboronates and Potassium cis-Alkenyltrifluoroborates via a Hydroboration/Protodeboronation Approach," J. Org. Chem., 73, 6841–6844 (2008).
S. D. Dreher, P. G. Dormer, D. L. Sandrock, G. A. Molander, "Efficient Cross-Coupling of Secondary Alkyltrifluoroborates with Aryl Chlorides—Reaction Discovery Using Parallel Micro-Scale Experimentation," J. Am. Chem. Soc., 130, 9257–9259 (2008).
G. A. Molander, W. Febo-Ayala, M. Ortega-Guerra, "Facile Synthesis of Highly Functionalized Ethyltrifluoroborates," J. Org. Chem., 73, 6000–6002 (2008).
G. A. Molander, B. Canturk, "Preparation of Potassium Alkoxymethyltrifluoroborates and Their Cross-Coupling with Aryl Chlorides," Org. Lett., 10, 2135–2138 (2008).
G. A. Molander, D. J. Cooper, "Functionalization of Organotrifluoroborates: Reductive Amination," J. Org. Chem., 73, 3885–3891 (2008).
G. A. Molander, D. E. Petrillo, "Suzuki–Miyaura Cross-Coupling of Potassium Trifluoroboratohomoenolates," Org. Lett., 10, 1795–1798 (2008).
G. A. Molander, P. E. Gormisky, D. L. Sandrock, "Scope of Aminomethylations via Suzuki–Miyaura Cross-Coupling of Organotrifluoroborates," J. Org. Chem., 73, 2052–2057 (2008).
Y. H. Park, H. R. Ahn, B. Canturk, S. I. Jeon, S. Lee, H. Kang, G. A. Molander, J. Ham, "A Facile One-Pot Preparation of Potassium Hydroxyaryl- and (Hydroxyalkyl)aryltrifluoroborates," Org. Lett., 10, 1215–1218 (2008).
G. A. Molander, R. A. Oliveira, "Wittig Reaction of Formyl-Substituted Organotrifluoroborates and Stabilized Phosphonium Ylides in an Aqueous Medium," Tetrahedron Lett., 49, 1266–1268 (2008).
G. A. Molander, R. A. Oliveira, "Wittig Reaction of Formyl-Substituted Organotrifluoroborates and Stabilized Phosphonium Ylides in an Aqueous Medium," Tetrahedron Lett., 49, 1266–1268 (2008).


G. A. Molander, L. Jean-Gérard, "Scope of the Suzuki–Miyaura Aminoethylation Reaction using Organotrifluoroborates," J. Org. Chem., 72, 8422–8426 (2007).
G. A. Molander; D. E. Petrillo, "1-(4-Acetylphenyl)-2-Phenylethane from Potassium 2-Phenethyltrifluoroborate and 4-Bromoacetophenone," Org. Synth., 84, 317–324 (2007).
G. A. Molander, D. L. Sandrock, "Aminomethylations via Cross-Coupling of Organotrifluoroborates with Aryl Bromides," Org. Lett., 9, 1597–1600 (2007).
G. A. Molander, D. J. Cooper, "Ozonolysis of Unsaturated Organotrifluoroborates," J. Org. Chem., 72, 3558–3560 (2007).
G. A. Molander, B. Czakó, M. Rheam, "Construction of Bicyclic Ring Systems via a Transannular SmI2-Mediated Ketone-Olefin Cyclization Strategy," J. Org. Chem., 72, 1755–1764 (2007).
G. A. Molander, J. Ham, B. Canturk, "Preparation and Wittig Reactions of Organotrifluoroborato Phosphonium Ylides," Org. Lett., 9, 821–824 (2007).
G. A. Molander, J. Ham, D. G. Seapy, "Palladium-Catalyzed Cross-Coupling Reaction of Alkenyl Bromides with Potassium Alkyltrifluoroborates," Tetrahedron, 63, 768–775 (2007).
G. A. Molander, F. Vargas, "β-Aminoethyltrifluoroborates: Efficient Aminoethylations via Suzuki–Miyaura Cross-Coupling," Org. Lett., 9, 203–206 (2007).
G. A. Molander, N. M. Ellis, "Organotrifluoroborates: Expanding the Versatility of the Suzuki Coupling Reaction," Acc. Chem. Res., 40, 275–286 (2007).
D. E. Petrillo, R. K, Kohli, G. A. Molander, "Accurate Mass Determination of Organotrifluoroborates," J. Am. Soc. Mass. Spectrom., 18, 404–405 (2007).


G. A. Molander, M. D. Elia, "Suzuki–Miyaura Cross-Coupling Reactions of Benzyl Halides with Potassium Aryltrifluoroborates," J. Org. Chem., 71, 9198–9202 (2006).
G. A. Molander, A. R. Brown, "Suzuki–Miyaura Cross-Coupling Reactions of Potassium Vinyltrifluoroborates with Aryl- and Heteroaryl Electrophiles," J. Org. Chem., 71, 9681–9686 (2006).
G. A. Molander, N. M. Ellis, "Linchpin Synthons: Metalation of Aryl Bromides Bearing a Potassium Trifluoroborate Moiety," J. Org. Chem., 71, 7491–7493 (2006).
G. A. Molander, N. M. Ellis, "Linchpin Synthons: Metalation of Aryl Bromides Bearing a Potassium Trifluoroborate Moiety," J. Org. Chem., 71, 7491–7493 (2006).
G. A. Molander, D. E. Petrillo, "Oxidation of Hydroxyl-Substituted Organotrifluoroborates," J. Am. Chem. Soc., 128, 9634–9635, (2006).
G. A. Molander, T. Fumagalli, "Palladium(0)-Catalyzed Suzuki–Miyaura Coupling Reactions of Potassium Aryl- and Heteroaryltrifluoroborates with Alkenyl Bromides," J. Org. Chem., 71, 5743–5747 (2006).
GG. A. Molander, J. Ham, "Synthesis of Functionalized Organotrifluoroborates via the 1,3-Dipolar Cycloaddition of Azides," Org. Lett., 8, 2767–2770 (2006).
G. A. Molander, R. Figueroa, "Synthesis of Unsaturated Organotrifluoroborates via Wittig and Horner-Wadsworth-Emmons Olefination," J. Org. Chem., 71, 6135–6140 (2006).
G. A. Molander, J. Ham, "Synthesis of Functionalized Organotrifluoroborates via Halomethyltrifluoroborates," Org. Lett., 8, 2031–2034 (2006).
G. A. Molander, Y. Yokoyama, "One-Pot Synthesis of Trisubstituted Conjugated Dienes via Sequential Suzuki–Miyaura Cross-Coupling with Alkenyl- and Alkyltrifluoroborates," J. Org. Chem., 71, 2493–2498 (2006).
G. A. Molander, B. Czakó, D. J. St. Jean, Jr., "A General Route Toward the Synthesis of the Cladiellin Skeleton Utilizing a SmI2-Mediated Cyclization," J. Org. Chem., 71, 1172–1180 (2006).
G. A. Molander, E. M. Sommers, S. R. Baker, "Palladium(0)-Catalyzed Synthesis of Ene-allenes Using Alkenyl Trifluoroborates," J. Org. Chem., 71, 1563–1568 (2006).
G. A. Molander, E. M. Sommers, S. R. Baker, "Palladium(0)-Catalyzed Synthesis of Ene-allenes Using Alkenyl Trifluoroborates," J. Org. Chem., 71, 1563–1568 (2006).
M. Shenglof, G. A. Molander, J. Blum, "Cross-Coupling of Aryl Halides and Triflates with Group 13-Metal Alkylating Reagents by Palladium-Molybdenum and Palladium-Tungsten Mixed-Metal Catalysts," Synthesis, 111–114 (2006).
G. A. Molander, R. Figueroa, "cis-Dihydroxylation of Unsaturated Potassium Alkyl- and Aryltrifluoroborates," Org. Lett., 8, 75–78 (2006).


G. A. Molander, D. E. Petrillo, N. R. Landzberg, J. C. Rohanna, B. Biolatto, "Palladium-Catalyzed Suzuki–Miyaura Reactions of Potassium Aryl- and Heteroaryltrifluoroborates with Aryl- and Heteroaryl Triflates," Synlett, 1763–1766 (2005).
G. A. Molander, R. Figueroa, "Organotrifluoroborates: Expanding Organoboron Chemistry," Aldrichimica Acta, 38, 49–56 (2005).
G. A. Molander, L. A. Felix, "Stereoselective Suzuki–Miyaura Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates with Alkenyl Bromides," J. Org. Chem., 70, 3950–3956 (2005).
G. A. Molander, E M. Sommers, "Chromium(III) Catalyzed Synthesis of Allenes from Propargyl Derviatives via a Carbometalation-Elimination Sequence," Tetrahedron Lett., 46, 2345–2349 (2005).
G. A. Molander, E. Pollina-Cormier, "Ketyl-Allene Cyclizations Promoted by Samarium(II) Iodide," J. Org. Chem., 70, 2622–2626 (2005).
G. A. Molander, J. A. C. Romero, "Investigations Concerning the Organolanthanide and Group 3 Metallocene-Catalyzed Cyclization-Functionalization of Nitrogen-Containing Dienes," Tetrahedron, 61, 2631–2643 (2005).


G. A. Molander, J. P. Burke, P. J. Carroll, "Synthesis and Application of Chiral Cyclopropane-Based Ligands in Palladium-Catalyzed Allylic Alkylation," J. Org. Chem., 69, 8062–8069 (2004).
G. A. Molander, H. Hasegawa, "Organolanthanide Catalyzed Intramolecular 5-Endo-Dig Hydroamination: An Unusual Anti-Markovnikov Cyclization," Heterocycles, 64, 467–474 (2004).
G. A. Molander, F. Dehmel, "Formal Total Synthesis of Oximidine II via a Suzuki-Type Cross-Coupling Macrocyclization Employing Potassium Organotrifluoroborates," J. Am. Chem. Soc., 126, 10313–10318 (2004).
D. Tsvelikhovsky, D. Gelman, G. A. Molander, J. Blum, "Lanthanide-Promoted Ethylation of Schiff Bases by Triethylaluminum," Org. Lett., 6, 1995–1997 (2004).
G. A. Molander, D. J. St. Jean, Jr., J. Haas, "Toward a General Route to the Eunicellin Diterpenes: The Asymmetric Total Synthesis of Deacetoxyalcyonin Acetate," J. Am. Chem. Soc., 126, 1642–1643 (2004).
G. A. Molander, D. J. St. Jean, Jr., J. Haas, "Toward a General Route to the Eunicellin Diterpenes: The Asymmetric Total Synthesis of Deacetoxyalcyonin Acetate," J. Am. Chem. Soc., 126, 1642–1643 (2004).


G. A. Molander, S. K. Pack, "Determining the Scope of the Organolanthanide Catalyzed, Sequential Amination/Cyclization Reaction: Formation of Substituted Quinolizidines, Indolizidines, and Pyrrolizidines," J. Org. Chem., 68, 9214–9220 (2003).
G. A. Molander, S. K. Pack, "Determining the Scope of the Lanthanide Mediated, Sequential Hydroamination/C-C Cyclization Reaction: Formation of Tricyclic and Tetracyclic Aromatic Nitrogen Heterocycles," Tetrahedron, 59, 10581–10591 (2003).
M. Shenglof, D. Gelman, G. A. Molander, J. Blum, "Lanthanide Assisted Cross-Coupling of Aryl Bromides with Triethylaluminum," Tetrahedron Lett., 44, 8593–8595 (2003).
G. A. Molander, K. M. George, L. G. Monovich, "Total Synthesis of (+)-Isoschizandrin Utilizing a Samarium(II) Iodide Promoted 8-Endo Ketyl-Olefin Cyclization," J. Org. Chem., 68, 9533–9540 (2003).
G. A. Molander, B. P. Hoag, "Improved Synthesis of Potassium (Trifluoromethyl)trifluoroborate [K(CF3BF3)]," Organometallics, 22, 3313–3315 (2003).
G. A. Molander, C. -S. Yun, M. Ribagorda, B. Biolatto, "B-Alkyl Suzuki–Miyaura Cross-Coupling Reactions with Air Stable Potassium Alkyltrifluoroborates," J. Org. Chem., 68, 5534–5539 (2003).
G. A. Molander, M. Ribagorda, "Expanding Organoboron Chemistry. Epoxidation of Potassium Organotrifluoroborates," J. Am. Chem. Soc., 125, 11148–11149 (2003).
M. Shenglof, D. Gelman, B. Heymer, H. Schumann, G. A. Molander, J. Blum, "Cross-Coupling of Aryl Halides and Triflates with Intramolecularly Stabilized Group 13-Metal Alkylating Reagents in the Presence of Mixed-Metal Catalysts," Synthesis, 302–306 (2003).
G. A. Molander, B. Biolatto, "Palladium Catalyzed Suzuki–Miyaura Cross-Couping Reactions of Potassium Aryl- and Heteroaryltrifluoroborates," J. Org. Chem., 68, 4302–4314 (2003).


G. A. Molander, B. W. Katona, F. Machrouhi, "Development of the Suzuki–Miyaura Cross-Coupling Reaction: The Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations," J. Org. Chem., 67, 8416–8423 (2002).
G. A. Molander, C. R. Bernardi, "Suzuki–Miyaura Cross-Coupling Reaction of Potassium Alkenyltrifluoroborates," J. Org. Chem., 67, 8424–8429 (2002).
D. Gelman, D. Tsvelikhovsky, G. A. Molander, J. Blum, "Palladium-Catalyzed Cross-Alkynylation of Aryl Bromides by Sodium Tetraalkynylaluminates," J. Org. Chem., 67, 6287–6290 (2002).
G. A. Molander, C. T. Bibeau, "Thermal Rearrangements of α-(ω-Azidoalkyl) Enones," Tetrahedron Lett., 43, 5385–5388 (2002).
G. A. Molander, D. J. St. Jean, Jr., "Samarium(II) Iodide-Mediated Intramolecular Conjugate Additions of α,β-Unsaturated Lactones," J. Org. Chem., 67, 3861–3865 (2002).
G. A. Molander, G. A. Brown, I. Storch de Gracia, "Sequenced Reactions with Samarium(II) Iodide. Sequential Intramolecular Reformatsky/Nucleophilic Acyl Substitution Reactions for the Synthesis of Medium-Sized Carbocycles," J. Org. Chem., 67, 3459–3463 (2002).
G. A. Molander, B. Biolatto, "Efficient Ligandless Palladium Catalyzed Suzuki Reactions of Potassium Aryltrifluoroborates," Org. Lett., 4, 1867–1870 (2002).
G. A. Molander, C.-S. Yun, "Cross-Coupling Reactions of Primary Alkylboronic Acids with Aryl Triflates and Aryl Halides," Tetrahedron, 58, 1465–1470 (2002).
G. A. Molander, S. C. Jeffrey, "Synthesis of the Core Ring-System of the Sclerophytin Diterpenes Utilizing a Lewis Acid-Promoted [4+3] Annulation Strategy," Tetrahedron Lett., 43, 359–362 (2002).
G. A. Molander, J. A. C. Romero, "Lanthanocene Catalysts in Selective Organic Synthesis" Chem. Rev., 102, 2161–2185 (2002).
G. A. Molander, J. A. C. Romero, C. P. Corrette, "Hydrosilylation of Alkynylsilanes Utilizing Organolanthanides and Group 3 Metallocene Catalysts," J. Organomet. Chem., 647, 225–235 (2002).
G. A. Molander, M. Rodríguez-Rivero, "Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates," Org. Lett., 4, 107–109 (2002).


G. A. Molander, M. S. Quirmbach, L. F. Silva, Jr., K. C. Spencer, "Toward the Total Synthesis of Variecolin," Org. Lett., 3, 2257–2260 (2001).
G. A. Molander, Y. Le Huérou, G. A. Brown, "Sequenced Reactions with Samarium(II) Iodide. Sequential Intramolecular Barbier Cyclization/Grob Fragmentation for the Synthesis of Medium-Sized Carbocycles," J. Org. Chem., 66, 4511–4516 (2001).
G. A. Molander, E. D. Dowdy, S. K. Pack, "A Diastereoselective Intramolecular Hydroamination Approach to the Synthesis of (+)-, (±)- and (–)-Pinidinol," J. Org. Chem., 66, 4344–4347 (2001).
G. A. Molander, T. Ito, "Cross-Coupling Reactions of Potassium Alkyltrifluoroborates with Aryl- and 1-Alkenyl Trifluoromethanesulfonates," Org. Lett., 3, 393–396 (2001).
G. A. Molander, D. Pfeiffer, "Organolanthanide-Catalyzed Cyclization/Boration of 1,5- and 1,6-Dienes," Org. Lett., 3, 361–363 (2001).


G. A. Molander, C. Köllner, "Development of a Protocol for Eight- and Nine-Membered Ring Synthesis in the Annulation of sp2,sp3-Hybridized Organic Dihalides with Keto Esters," J. Org. Chem., 65, 8333–8339 (2000).
G. A. Molander, "Application of Group 3 and Lanthanide Metallocenes as Catalysts for Selective Organic Synthesis," Pure Appl. Chem., 72, 1757–1761 (2000).
G. A. Molander, M. H. Schmitt, "Organoyttrium-Catalyzed Sequential Cyclization/Silylation Reactions of Nitrogen-Heteroaromatic Dienes Demonstrating 'Aryl-Directed' Regioselectivity," J. Org. Chem., 65, 3767–3770 (2000).
G. A. Molander, R. M. Rzasa, "Hetero Diels–Alder Reactions Catalyzed by the Metallocenium Complex   [Cp*2Ce][BPh4]," J. Org. Chem., 65, 1215–1217 (2000).
L. Gilchrist-Monovich, Y. Le Huérou, M. Rönn, G. A. Molander, "Total Synthesis of (–)-Steganone Utilizing a Samarium(II) Iodide Promoted 8-Endo Ketyl-Olefin Cyclization," J. Am. Chem. Soc., 122, 52–57 (2000).